Non-equilibrium electron transport in donor-bridge-acceptor systems
Electron transport between a donor and an acceptor mediated by a bridge has a fundamental role in a wide set of areas. These include: biological redox systems where electron transport through an intervening bridge is central to photosynthesis, enzyme catalyzed reactions, advanced materials including photo-voltaics, molecular nano-electronic, charge transfer in DNA and large biomolecules and atmospheric and condensed phase systems where solvated electron chemistry plays an important role. In materials chemistry, active research in molecular electronics has been triggered partly by the possibility of silicon based electronic chip technology tending to its inherent physical limitations and through novel developments in nano-fabrication methods. In addition many of the challenges encountered here are also relevant to photo-voltaic systems and solar energy conversion and storage. The intensity of current research effort in these areas is due to the expectation that electronic transport properties may be tailored with tools of synthetic and surface chemistry To this extent, electronic and optical properties of numerous single molecules, organic self assembled monolayers (SAMs) and carbon nanotubes have been the subject of earnest experimental and theoretical pursuit.
